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Record W4414362969 · doi:10.1088/1681-7575/ae093d

Uncertainty analysis of MSL’s CCT-K7.2021 key comparison measurements taking account of correlations

2025· article· en· W4414362969 on OpenAlexaboutno aff
Ellie Molloy, Peter M. Saunders

Bibliographic record

VenueMetrologia · 2025
Typearticle
Languageen
FieldEnvironmental Science
TopicWater Quality Monitoring and Analysis
Canadian institutionsnot available
Fundersnot available
KeywordsMeasurement uncertaintyUncertainty analysisTransfer (computing)Standard uncertaintyVariation (astronomy)Key (lock)Sensitivity analysisPoint (geometry)

Abstract

fetched live from OpenAlex

Abstract The National Research Council of Canada (NRC) recently piloted the second international key comparison of triple point of water cells, CCT-K7.2021, where participants submitted a transfer cell and a report of the temperature difference between their transfer cell and their respective national reference. By comparing the differences between each transfer cell, NRC could calculate the differences between each participant’s national reference. While there was good agreement among all the participants, there was a large variation among the submitted uncertainties. This was possibly due to the complexity of the uncertainty analysis, which typically has many correlated components between the transfer cell and the national reference that partially cancel when the difference is taken. The Measurement Standards Laboratory of New Zealand (MSL) carried out its analysis using a detailed measurement model that included all known correlations and applied an algorithmic approach fully compliant with the Guide to the Expression of Uncertainty in Measurement . As a consequence, MSL submitted an uncertainty value less than half the uncertainty values submitted by almost all of the other participants. This paper describes the measurement model implemented by MSL and demonstrates how accounting correctly for correlations leads to a significantly lower uncertainty. The paper also shows how applying the same method to the previously published NRC analysis results in a reduction in the NRC uncertainty by a factor of about 2.5, making it smaller than the MSL uncertainty.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.150
Threshold uncertainty score0.760

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.002
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.060
GPT teacher head0.327
Teacher spread0.267 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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