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Record W4414832423 · doi:10.1016/j.nexres.2025.100900

Determination of fingerprint by Hplc-Uv of improved traditional medicines to combat the marketing of substandard and falsified medicines

2025· article· en· W4414832423 on OpenAlex
J.M. Bapite, P.N. Ntondele, M.M. Phuati, M.N. Ntambwe, G. Lakshmi Sita, J. Mwanga, Jocelyn Mankulu Kakumba, J.K. Mbinze

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueNext research. · 2025
Typearticle
Languageen
FieldMedicine
TopicPharmaceutical Quality and Counterfeiting
Canadian institutionsUniversité du Québec à Montréal
Fundersnot available
KeywordsQuality (philosophy)Trifluoroacetic acidHarmonizationFingerprint (computing)Phase (matter)

Abstract

fetched live from OpenAlex

Improved traditional medicines (ITMs) are increasingly used worldwide, but quality control still poses challenges due to the lack of official analytical methods. This makes it impossible to guarantee their quality, efficacy, and safety. The primary aim of this study was to develop an analytical method using High-Performance Liquid Chromatography (HPLC) to characterise the chemical profiles of improved traditional medicines (ITMs) marketed in the Democratic Republic of Congo. This was followed by the validation of the developed method and its routine application. Chromatographic separation was performed using the XBridge C18 column (250 × 4.6 mm internal diameter; 5 µm particle size), maintained at 25 °C. The mobile phase consisted of a gradient mixture of mobile phases A (acetonitrile) and B (0.05 % aqueous trifluoroacetic acid solution), pumped at 1.0 mL/min. UV detection was carried out at 220 nm. A generic method was developed that proved to be specific, linear (R² > 0.990), accurate (RSD < 10 %), and precise. The validated method was successfully applied to 12 real samples marketed in Kinshasa (capital of DR Congo). The validated HPLC method proves to be a reliable tool for ITM quality control. This method allows for the simultaneous analysis of multiple biomarkers in an ITM. Its routine use would support the harmonization and safety of these plant-based products, which are widely utilized in the DRC, and encourage scientifically supervised traditional medicine.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.005
metaresearch head score (Gemma)0.004
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.153
Threshold uncertainty score0.457

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0050.004
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.167
GPT teacher head0.450
Teacher spread0.283 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it