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Record W4414957829 · doi:10.1073/pnas.2522352122

Guanine storage vacuoles sequester guanine crystals and serve as nitrogen reserves in <i>Chlamydomonas reinhardtii</i>

2025· article· en· W4414957829 on OpenAlexafffund
Ursula Goodenough, Robyn Roth, Jae-Hyeok Lee

Bibliographic record

VenueProceedings of the National Academy of Sciences · 2025
Typearticle
Languageen
FieldPhysics and Astronomy
TopicSpectroscopy and Quantum Chemical Studies
Canadian institutionsUniversity of Manitoba
FundersRES’EAU-WaterNETNatural Sciences and Engineering Research Council of CanadaOffice of Energy Efficiency and Renewable EnergyInternational Center for Energy, Environment and Sustainability, Washington University in St. LouisU.S. Department of Energy
KeywordsGuanineVacuoleCytoplasmContext (archaeology)Raman spectroscopyAmorphous solid

Abstract

fetched live from OpenAlex

Nitrogen cycles in Chlamydomonas reinhardtii have historically been studied in the context of exogenous ammonium/nitrate availability and uptake. Recently, crystalline guanine has been identified, using Raman microscopy, in the cytoplasm of numerous microalgae, including C. reinhardtii . The signal level is influenced by availability of exogenous nitrogen, suggesting that the deposits serve as a nitrogen store. We report the visualization of these guanine crystals in C. reinhardtii and other microalgae using quick-freeze deep-etch electron microscopy. They prove to reside within cytoplasmic vacuoles: A membrane with a high density of small intramembranous particles surrounds a uniform, coarsely granular interior matrix within which stacks of flat crystals assemble, often in stunning abundance. We designate these as guanine storage vacuoles (GSVs). In C. reinhardtii and other members of the Chlamydomonadales, a discrete disc-shaped granular domain occupies the center of each GSV, and the crystals arise within or at the edges of this domain, suggesting that it represents an amorphous form of guanine. In C. reinhardtii , GSVs are numerous in log-phase cells, are not found in cells maintained in nitrogen-free medium, and reappear within 8 h after the cells are provided with nitrogen, initially as small disc-containing vacuoles. We compare this cycle with that of the polyphosphate granules localized in acidocalcisomes. Nineteen enzyme families and 10 transporters are predicted to participate in guanine-related pathways in C. reinhardtii , many showing strong upregulation with nitrogen starvation. These understandings will inform future studies on the contributions made by GSVs to the metabolism and physiology of eukaryotic microalga.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.006
Threshold uncertainty score0.012

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0000.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.023
GPT teacher head0.317
Teacher spread0.294 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2025
Admission routes2
Has abstractyes

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