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Record W4415471551 · doi:10.1039/d5em00615e

Emerging investigator series: unpacking PET: comparative analysis of leachable and extractable contaminants from virgin and recycled polyethylene terephthalate bottles and textiles

2025· article· en· W4415471551 on OpenAlexafffund
Yanan Li, Eric Fries, Jeff Gearhart, Dayton McGrail, Christopher D. Kassotis, Roxana Sühring

Bibliographic record

VenueEnvironmental Science Processes & Impacts · 2025
Typearticle
Languageen
FieldEnvironmental Science
TopicEnvironmental Impact and Sustainability
Canadian institutionsToronto Metropolitan UniversityUniversity of Toronto
FundersNatural Sciences and Engineering Research Council of CanadaMarisla FoundationPark Foundation
KeywordsPolyethylene terephthalateContaminationHazardous wasteDiethylene glycolLaundryBottleLeaching (pedology)Human health

Abstract

fetched live from OpenAlex

Plastics, particularly polyethylene terephthalate (PET), are widely used as food contact materials, textiles, and toys. However, their widespread use and potential for human exposure raise environmental and health concerns, particularly regarding the leaching of chemical additives. This study assessed hazardous plastic additives and non-intentionally added substances (NIAS) leached from paired virgin and recycled PET bottles (soda and water) purchased from Michigan and California and from textiles (toys, pillows, and clothing) acquired online or in stores in Michigan and Oregon. Results showed differences in contaminant profiles and concentrations between PET types and products. A total of 12 persistent, mobile, and toxic (PMT) additives, six organophosphate esters (OPEs), and 15 NIAS were detected. Notably, recycled PET (rPET) bottles consistently contained benzene, while virgin PET had higher ethylene glycol and 2-methyl-1,3-dioxolane levels. Additionally, OPEs were detected more frequently in rPET, indicating recycling as a contamination pathway. Geographically distinct contaminant profiles were evident, with Michigan bottles exhibiting elevated benzaldehyde, while California bottles showed higher diethylene glycol levels, suggesting differing manufacturing practices. Textiles exhibited distinct contamination profiles, highlighting a distinct exposure pathway for watersheds through laundry processes. Bioactivity assays with PET product extracts revealed moderate to high hormone receptor antagonism but no clear association with PET type, indicating potential hazardous effects from both virgin and recycled PET products. This study highlights the necessity of continued monitoring of contaminants in PET, including non-intentionally added substances and PMT plastic additives that are not currently regulated.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.213
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0010.004
Scholarly communication0.0000.002
Open science0.0000.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.266
Teacher spread0.259 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes2
Has abstractyes

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