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Record W4415981463 · doi:10.1021/acsinfecdis.5c00539

Chemical Profiling of <i>Candida albicans</i> Growth Phases by Vibrational Spectroscopy

2025· article· en· W4415981463 on OpenAlexaff
Savithri Pebotuwa, Xenia Kostoulias, Bayden R. Wood, Anton Y. Peleg, Kamila Kochan

Bibliographic record

VenueACS Infectious Diseases · 2025
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicSpectroscopy Techniques in Biomedical and Chemical Research
Canadian institutionsImpact
FundersNational Health and Medical Research CouncilAustralian Government
KeywordsPrincipal component analysisExponential growthSpectroscopyPartial least squares regressionAnalytical Chemistry (journal)Infrared spectroscopyFourier transform infrared spectroscopyInfraredChemometrics

Abstract

fetched live from OpenAlex

Candida albicans is an opportunistic fungal pathogen whose growth phase-dependent chemical changes play a critical role in its physiology, pathogenicity, and response to treatment. Here, vibrational spectroscopy combined with chemometric models was applied to investigate differences in spectral signatures of C. albicans yeast cells across different growth phases. C. albicans isolated from different clinical presentations were subjected to spectral analysis at multiple time points over a 24 h period using a Fourier Transform Infrared (FTIR) spectrometer with a built-in Attenuated Total Reflectance (ATR) device. Principal Component Analysis (PCA) and Partial Least Squares Regression analysis (PLS-R) demonstrated that exponential phase and stationary phase time points were spectroscopically distinct based on variations in protein, lipid, polysaccharide, and DNA bands. Across the chemometric methods, the bands associated with glucans, chitin and mixed mannan, and DNA were significant, with the mannan band emerging as a distinctive feature of stationary phase time points in both analytical approaches. Notably, the PLS-R analysis yielded a strong linear correlation between time points and spectral bands, highlighting the reliability of these spectroscopic signatures in characterizing growth phases. This comprehensive analysis highlights the distinct spectroscopic profiles associated with C. albicans growth phases, shedding light on the intraphase chemistry of yeast cells. Our findings underscore the potential of vibrational spectroscopy as a valuable tool for investigating the dynamics of fungal growth and inform future advances in diagnostics and therapeutic strategies for fungal infections.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.055
Threshold uncertainty score0.598

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.287
Teacher spread0.283 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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