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Record W4416081794 · doi:10.1021/cbmi.5c00113

Ion Beam Imaging Shows Selective Thallium-201 Uptake in Cell Nuclei: Impact on Cellular Dosimetry and Radiotoxicity of Auger Electron Emitters

2025· article· en· W4416081794 on OpenAlexaff
Katarzyna M. Wulfmeier, Paul Gape, Catia Costa, P. Machado, Theodora J. Stewart, Raymond M. Reilly, Melanie J. Bailey, Philip J. Blower, Vincenzo Abbate, Samantha Y.A. Terry

Bibliographic record

VenueChemical & Biomedical Imaging · 2025
Typearticle
Languageen
FieldMedicine
TopicRadiopharmaceutical Chemistry and Applications
Canadian institutionsPrincess Margaret Cancer CentreUniversity of TorontoUniversity Health Network
FundersEngineering and Physical Sciences Research CouncilMedical Research CouncilUK National Ion Beam CentreWellcome Trust
KeywordsDU145Absorbed doseDosimetryAuger effectAuger electron spectroscopyNucleusGliosarcomaIonRadionuclide therapy

Abstract

fetched live from OpenAlex

High Resolution Image Download MS PowerPoint Slide Thallium-201, a promising candidate for precise targeted radionuclide therapy, emits abundant, radiotoxic, short-range Auger and other secondary electrons, but its subcellular distribution, on which the delivered absorbed radiation dose depends, remains unknown. This study investigates the subcellular localization of unbound 201 Tl +, for input into microdosimetry models. Methods: Prostate (DU145), ovarian (SKOV3), and lung (A549) cancer cells were exposed to nonradioactive TlCl and imaged using laser ablation-inductively coupled plasma-mass spectrometry, energy-dispersive X-ray spectroscopy combined with transmission electron microscopy, and ion beam analysis (IBA). Absorbed radiation doses to cell nuclei from intracellular 201 Tl were calculated for geometries based on DU145 cells, applying the standard Medical Internal Radiation Dose formalism, and compared to those from 201 Tl-labeled Prussian blue nanoparticles (PBNPs). Results: Only IBA successfully quantified thallium in both the nucleus and cytoplasm, showing selective uptake in the nucleus with nuclear:cytoplasmic concentration ratios of 1.8 ± 1.5 in DU145 cells and 1.8 ± 1.0 in SKOV3 cells. New dose calculations for 201 Tl revealed that exclusively cytoplasmic localization of 201 Tl activity, exemplified by 201 Tl bound to chitosan-coated PBNPs in A549 cells, reduces the absorbed dose to the nucleus by 82%, compared to the observed distribution of unbound 201 Tl +, providing a rationale for reduced cytotoxicity per decay for PBNPs compared to 201 Tl + observed previously. Conclusion: Thallium(I) ions show preferential accumulation in cell nuclei and this could account for the higher toxicity of [ 201 Tl]TlCl than [ 201 Tl]PBNPs per intracellular decay event.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.302
Teacher spread0.295 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2025
Admission routes1
Has abstractyes

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