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Disinfection byproducts and cellular toxicity from UV/chlorine advanced oxidation for potable reuse and drinking water treatment compared to chlorination and UV/hydrogen peroxide

2025· article· en· W4417408694 on OpenAlexafffund
Liz Taylor-Edmonds, Nicole Zollbrecht, Kirsten Yeung, Jianxian Sun, Kevin Legaspi-Annett, Katie Vanyo, Gabriela Barreto Bossoni, Tianyi Chen, Vishal Manek, Erin Mackey, Susan Andrews, Ron Hofmann

Bibliographic record

VenueThe Science of The Total Environment · 2025
Typearticle
Languageen
FieldEnvironmental Science
TopicAdvanced oxidation water treatment
Canadian institutionsHudbay Minerals (Canada)University of Toronto
FundersUniversity of TorontoNatural Sciences and Engineering Research Council of CanadaWater Research FoundationHampton Roads Sanitation DistrictCalifornia State Water Resources Control Board
KeywordsChlorineReuseWater treatmentPotable waterToxicityPortable water purificationContamination

Abstract

fetched live from OpenAlex

This work explored treatment byproducts and cellular toxicity resulting from UV/chlorine advanced oxidation for potable water reuse and drinking water treatment, in comparison to chlorine and UV/hydrogen peroxide as treatments widely considered acceptable to use. Waters from six full or large demonstration-scale potable water reuse or drinking water treatment plants were treated with lab and pilot-scale UV/chlorine, chlorine alone, and UV/hydrogen peroxide and analyzed for 43 known disinfection byproducts and four types of cellular toxicity. The byproducts and toxicity were almost always near or below detection limits for waters treated with reverse osmosis. For the other waters, UV/chlorine generally led to small (< 10 μg/L or < 40 %) increases in the byproduct concentrations over chlorine alone, though cellular toxicity following the two treatments was similar. While UV/chlorine formed more byproducts than UV/hydrogen peroxide within the UV reactor, there was little difference in the byproducts and cellular toxicity between the waters treated by either AOP plus secondary chlorination. One UV/chlorine byproduct of potential concern observed in this work was chlorate, as up to 15 % of the chlorine photolyzed during UV/chlorine converted to chlorate.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.068
Threshold uncertainty score0.417

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0010.001
Scholarly communication0.0000.000
Open science0.0000.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.216
Teacher spread0.207 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2025
Admission routes2
Has abstractyes

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