Additional file 1 of Synthesis, characterization, and antibacterial activity studies of two Co(II) complexes with 2-[(E)-(3-acetyl-4-hydroxyphenyl)diazenyl]-4-(2-hydroxyphenyl)thiophene-3-carboxylic acid as a ligand
Bibliographic record
Abstract
Additional file 1: Figure S1. Powder X-ray diffractogram of compound 11. Figure S2. UV-VIS spectrum of compound 11. Figure S3. IR spectrum of compound 11 with some assignments. Figure S4. HRESI+ mass spectrum of compound 11. Figure S5. 1H-NMR spectrum of compound 11. Figure S6. 13C-NMR spectrum of compound 11. Figure S7. HSQC spectrum of compound 11. Figure S8. COSY 1H-1H spectrum of compound 11 with some correlations. Figure S9. HMBC spectrum of compound 11. Figure S10. UV-VIS spectrum of complex 12. Figure S11. IR spectrum of complex 12. Figure S12. HRESI+ mass spectrum of complex 12. Figure S13. 1H-NMR spectrum of complex 12. Figure S14. 13C-NMR spectrum of complex 12. Figure S15. HSQC spectrum of complex 12 with some correlations. Figure S16. COSY 1H-1H spectrum of complex 12. Figure S17. HMBC spectrum of complex 12 with some correlations. Figure S18. Comparison of the UV-VIS spectra of compound 11 (black) and 12 (blue). Figure S19. Comparison of the IR spectra of compounds 11 (black) and 12 (blue). Figure S20. Comparison of the 1H-NMR spectra of compounds 11 (a) and 12 (b). Figure S21. Comparison of the 13C-NMR spectra of compounds 11 (a) and 12 (b). Figure S22. Powder X-ray diffractogram of compound 13. Figure S23. UV-VIS spectrum of compound 13. Figure S24. IR spectrum of compound 13. Figure S25. HRESI+ mass spectrum of compound 13. Figure S26. 1H-NMR spectrum of compound 13. Figure S27. 13C-NMR spectrum of compound 13. Figure S28. HSQC spectrum of compound 13 with some correlations. Figure S29. COSY 1H-1H spectrum of compound 13. Figure S30. HMBC spectrum of compound 13 with some correlations. Figure S31. Comparison of the powder X-ray diffractograms of compounds 11 (black) and 13 (green). Figure S32. Comparison of the UV-VIS spectra of compound 11 (black) and 13 (green). Figure S33. Comparison of the IR spectra of compounds 11 (black) and 13 (green). Figure S34. Comparison of the 1H-NMR spectra of compound 11 (a) and 13 (b). Figure S35. Comparison of the 13C-NMR spectra of compound 11 (a) and 13 (b).
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.291 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".