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Total Gaseous Mercury (TGM)

2014· dataset· en· W6925581355 on OpenAlexaffabout

Bibliographic record

VenueECCC Data Catalogue · 2014
Typedataset
Languageen
FieldMedicine
TopicMicrobial Natural Products and Biosynthesis
Canadian institutionsGovernment of QuebecEnvironment and Climate Change CanadaGovernment of Canada
Fundersnot available
KeywordsMercury (programming language)CartridgeThermal desorptionSpectrum analyzerQuality standardInletMERCURE

Abstract

fetched live from OpenAlex

At all locations the TGM measurements were made using automatic Tekran ® 2537 mercury vapour analyzers (described in detail in Poissant, 1997). The air is typically sampled at flow rates between 1.0 and 1.5 L/min (depending on location) and is passed through a Teflon filter (47 mm diameter; 0.45 µm) at the sample line inlet to remove particulate matter. Inside the analyzer, the mercury in the sample air is pre-concentrated before analysis by amalgamation on gold cartridges (5-30 minute concentration time). Mercury is removed from the gold cartridges by thermal desorption and is detected using Cold Vapour Atomic Fluorescence Spectrophotometry (CVAFS). The analyzer has two gold cartridges which allow alternating accumulation and desorption to occur simultaneously resulting in the continuous measurement of mercury in the air stream at 5-30 minute intervals. The instruments are calibrated daily using an internal mercury source and verified during routine site audits by manual injections of mercury from an external source. The data are quality controlled using the Environment Canada RDMQ (Research Data Management and Quality Control) system.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.004
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Dataset · Consensus signal: Dataset
Teacher disagreement score0.031
Threshold uncertainty score0.061

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.004
Meta-epidemiology (narrow)0.0020.000
Meta-epidemiology (broad)0.0020.001
Bibliometrics0.0050.009
Science and technology studies0.0010.000
Scholarly communication0.0020.001
Open science0.0020.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0180.022

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.030
GPT teacher head0.280
Teacher spread0.249 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreDataset

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2014
Admission routes2
Has abstractyes

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Same venueECCC Data CatalogueSame topicMicrobial Natural Products and BiosynthesisFrench-language works237,207