The novel sequential insertion of carbon monoxide and imines into palladium-carbon [sigma]-bonds : synthesis, mechanism and reactivity
Bibliographic record
Abstract
L'auteur a accord une cence non exclusive pennettant la Bibliothque oatiouale du Canada de reproduire, prter, distribuer ou vendre des copies de cette thse sous la forme de microfiche/film, de reproduction sur papier ou sur format lectronique.L'auteur conserve la proprit du droit d'auteur qui protge cette thse.Ni la thse ni des extraits substantiels de celle-ci ne doivent tre imprims ou autrement reproduits sans son autorisation.0-612-69867-X Canadl l'addition oxydante du CO ses sels d'iminiums N-acyles ToICH)C=NCCH 2 Ph)COPh+Cr au Pd2dba3-CHCh en prsence de 2,2'-bipyridine, rsulte la formation de drivs de palladium lis un a-amino acide~qui est suivi par un couplage avec l'imine.Cette raction a t tendue un couplage en 4 0ne pot' entre le catalyseur palladium coupl l'imine, le monoxyde de carbone et l'acide chlorhydrique pour donner des drivs de carboxylate d'imidazoline.La mthodologie dcrite offre une voie d'accs facile aux drivs biologiques de l'imidazoline travers l'insertion squentielle du CO et de l'imine dans les liaisons palladium-alkyles (chapitre 5).v AckDowledgments 1 am most grateful and thankful ta Allah, the most gracious, the most merciful, for ail the blessings he bestowed on my family, and me, and for giving us the power and the patience ta deal with our difficulties and challenges.1 would like to express my sincere gratitude ta my
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.001 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.001 | 0.002 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".