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Record W7067499550

Lethal and sub-lethal defects demonstrate the chronic toxicity of chemically-dispersed diluted bitumen to rainbow trout embryos (Oncorhynchus mykiss)

2017· dissertation· en· W7067499550 on OpenAlexaboutno aff

Bibliographic record

VenueQSpace (Queen's University Library) · 2017
Typedissertation
Languageen
FieldChemistry
TopicPetroleum Processing and Analysis
Canadian institutionsnot available
Fundersnot available
KeywordsRainbow troutChronic toxicityToxicityAcute toxicityPollutantEmbryoHatchingAsphaltDiluent
DOInot available

Abstract

fetched live from OpenAlex

Addition of a low molecular weight diluent to raw bitumen from Alberta’s Oil Sands produces diluted bitumen (dilbit), a physically and chemically distinct product from conventional oils. While thousands of kilometers of pipeline carry dilbit across Canada, relatively few studies have documented its environmental behaviour and toxicity to developing fish in the event of a spill to freshwater. In response, this study demonstrated exposure-response relationships between dilbit at a gradient of concentrations and toxicological responses of rainbow trout embryos under standardized laboratory conditions. Chronic toxicity was measured by exposing rainbow trout embryos for 25 days to two different winter dilbit blends, Access Western Blend (AWB) and Cold Lake Blend (CLB). Chemical dispersion of hydrocarbons from AWB and CLB dilbit into water (producing chemically enhanced water accommodated fractions, CEWAFs) was used to prepare exposure solutions. Endpoints to characterize chronic toxicity included mortality, impairment of growth and development, and select morphological deformities collectively called blue sac disease (BSD). Results indicated that cumulative mortality and the prevalence of sub-lethal defects (i.e. impairment of growth and development and onset of BSD) increased with increasing exposure concentration of dilbit CEWAF in water. Additionally, at the same volume of CEWAF, CLB had a higher total petroleum hydrocarbon content and higher lethal toxicity to rainbow trout embryos (25-d LC50 = 1200 g/L) than AWB (25-d LC50 = 1627 g/L). AWB and CLB were 2 and 2.7 times more toxic respectively when compared to a light crude oil (22-d LC50 = 3281 g/L), and 3.4 and 2.5 times less toxic respectively when compared to a heavy fuel oil (25-d LC50 = 473 g/L). This research contributes to developing a dilbit-specific assessment of toxicity and potential impacts (i.e., recruitment failure and declining populations of fish species whose spawning coincides with an oil spill) if the product is spilled into a freshwater environment.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.006
Threshold uncertainty score0.012

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.200
Teacher spread0.194 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2017
Admission routes1
Has abstractyes

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