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Record W7077082227 · doi:10.1002/cjce.70046

Polypropylene hollow fibre membranes treated with grafted‐aminated poly (glycidyl methacrylate) in the gas mixture separation

2025· article· en· W7077082227 on OpenAlexvenueno aff

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2025
Typearticle
Languageen
FieldComputer Science
TopicGeochemistry and Geologic Mapping
Canadian institutionsnot available
FundersCornell University - Department of City and, Regional Planning
KeywordsGlycidyl methacrylateAdsorptionPolypropyleneFourier transform infrared spectroscopyScanning electron microscopeVolumetric flow rateGraftingPolymerization

Abstract

fetched live from OpenAlex

Abstract Bonding polymerization is a straightforward and efficient approach for enhancing the quality of adsorbents and improving the properties of polymers and their bonding chains. The objective of this research was to enhance the ability of polypropylene hollow fibres to adsorb CO 2 . The surface of the adsorbent was modified using gamma irradiation in combination with glycidyl methacrylate and different amines, such as ethanolamine, triethylamine, and diethylamine. The efficacy of the modification process was evaluated by altering the graft variables, such as monomer concentration and gamma dose rate to determine the grafting degree (GD, %). Similarly, the amination yield (DA, %) was controlled through changes in the amine parameters, including amine type and concentration. Scanning electron microscope (SEM) techniques were used to examine the morphology of the modified hollow fibre membrane, while Fourier transform infrared spectroscopy (FTIR) was utilized to analyze the chemical structures of the fibres. Subsequently, the impact of gas flow intensity at the CO 2 inlet, with flow rates of 50, 100, and 150 cm 3 /min, and concentrations of 5%, 10%, and 15%, was investigated. The adsorption rate decreased significantly with an increase in gas flow rate at the inlet due to the short contact time and quick saturation. Additionally, the adsorption rate decreases notably with the increment of CO 2 concentration. The findings of this study indicate that the utilization of radiation resulted in the creation of a unique adsorbent with exceptional adsorption capabilities. Furthermore, this adsorbent was effectively recognized during the process of carbon dioxide adsorption.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.001

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.193
Teacher spread0.188 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

Explore more

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