IN-SITU STABILIZATION OF CACO3 POLYMORPHS IN CEMENTITIOUS SYSTEMS
Bibliographic record
Abstract
The technology of injecting CO2 in a cementitious system (concrete) during mixing has demonstrated scalability and significant potential. This process involves CO2 dissolving in water, releasing carbonate and bicarbonate ions that react with calcium ions from dissolving clinker and hydrate phases, leading to in-situ CaCO3 precipitation. This study examines CaCO3 formation pathways and explores stabilizing favourable polymorphs using additives. Cement paste samples were analyzed using FTIR and X-ray diffraction. Initial results suggest CaCO3 formation follows Ostwald's process. In early hydration (up to 6 hours), amorphous calcium carbonate and metastable crystalline polymorphs (vaterite and aragonite) form. These metastable forms then crystallize into calcite, the most stable polymorph, observed at 24 hours and beyond. Various amino acids (e.g., L-Arginine, L-Aspartic acid) are being tested to stabilize metastable polymorphs. Preliminary findings indicate these acids can successfully stabilize metastable polymorphs in-situ within CO2-injected cementitious systems.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".