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Record W7115812438

ELECTROPLATING NICKEL ONTO GALLIUM ARSENIDE AND GALLIUM PHOSPHIDE NANOWIRES FOR BETAVOLTAIC APPLICATIONS

2025· dissertation· en· W7115812438 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueMacSphere (McMaster University) · 2025
Typedissertation
Languageen
FieldEnergy
TopicAdvanced Energy Technologies and Civil Engineering Innovations
Canadian institutionsMcMaster UniversityCarleton University
Fundersnot available
KeywordsElectroplatingGallium arsenideNanowireGallium phosphidePlating (geology)NickelIndium phosphideGallium
DOInot available

Abstract

fetched live from OpenAlex

Betavoltaic (BV) devices represent a promising alternative energy technology, offering long-lasting, maintenance-free power for applications in remote, harsh, or inaccessible environments. Their performance is often limited by self-absorption of beta particles and inefficient carrier collection in conventional planar geometries. To address these challenges, this work investigates the conformal electroplating of nickel (Ni), and ultimately radioisotope nickel-63 in the future, onto gallium arsenide (GaAs) and gallium phosphide (GaP) NWs for use in BV devices. A systematic evolution of electroplating cell designs - from a simple beaker configuration to a custom Teflon cell - was carried out to optimize uniformity, reproducibility, and current efficiency. Direct current (DC) and pulsed electroplating methods were evaluated across NW arrays of varying pitch (360 nm, 600 nm, and 1000 nm). Results demonstrate that pulsed electroplating significantly mitigates mass diffusion limitations compared to DC plating, improving conformality along NW sidewalls. Optimal plating conditions were found to depend strongly on the interplay between on-time, off-time, and lateral diffusion times within NW arrays. These findings provide a framework for achieving controlled Ni coatings on III–V NWs, representing a key step toward high-efficiency, nanoscale BV devices.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.985
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.001
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.205
Teacher spread0.197 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it