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Record W7132910960

Extraction of Clove Oil with Lecithin-based Microemulsions Guided by the Hydrophilic-Lipophilic-Difference (HLD) and Net-Average-Curvature (NAC) Model

2022· dissertation· W7132910960 on OpenAlexaff
Jia Xin Tan

Bibliographic record

VenueTSpace · 2022
Typedissertation
Language
FieldChemistry
TopicSurfactants and Colloidal Systems
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsExtraction (chemistry)Pulmonary surfactantMicroemulsionPolarYield (engineering)Capillary actionSolventAqueous two-phase systemAqueous solution
DOInot available

Abstract

fetched live from OpenAlex

Current methods for extracting herbal oils, including steam and solvent extraction, suffer from low yields, using large volumes of solvents, and for being time and energy intensive. Capillary displacement, as an emerging extraction method, uses dilute surfactant solutions to promote low interfacial tensions to reduce the capillary pressure that retains triglycerides on the seed matrix. This work adapts this strategy to extract polar oils, specifically eugenol. Polar oils are compounds with dual, surfactant- and oil-like behaviour and their high affinity for the surfactant alters the phase behavior and make separating them from the surfactant difficult. The Hydrophilic-Lipophilic-Difference and Net-Average-Curvature + polar oil models are applied to predict the influence of eugenol in lecithin-based microemulsions and as a guide to develop an extraction process called Solvent-Addition and Self-Emulsification, that including a recycling step for the aqueous phase, produced 18% yield at room temperature and pressure with 5 minutes of extraction time.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.329
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.291
Teacher spread0.276 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2022
Admission routes1
Has abstractyes

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