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Record W7132930999

DEVELOPMENT OF LOW SMOKE ZERO HALOGEN POLYMER COMPOSITE FOR WIRE AND CABLE APPLICATION

2024· dissertation· W7132930999 on OpenAlexaff
Dina Castelletto

Bibliographic record

VenueTSpace · 2024
Typedissertation
Language
FieldMaterials Science
TopicFlame retardant materials and properties
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsFire retardantPolymerSmokeComposite numberCompatibility (geochemistry)Halogen
DOInot available

Abstract

fetched live from OpenAlex

Polymers are used in a multitude of applications in our daily lives, including components in wire and cable industries. While polymers are very versatile and useful materials, they are not thermally stable and when exposed to heat, can break down and lead to fire spread. In order to overcome this, flame retardant additives are introduced to a polymer system, providing flame retardancy. However, flame retardants that pose a risk to the environment and human health are in the process of being banned by many governments. Low smoke zero halogen flame retardants do not pose a large risk to human health and the environment, and the motivation for this study arises from the need of continuing development into flame resistant materials that use flame retardants that have no known environmental effects. This thesis studies the capabilities of low smoke zero halogen polymer composites in a few areas such as flame retardancy, thermal stability, and mechanical performance. The change in flame retardancy, thermal stability, and mechanical performance from neat material to polymer composite is characterized, along with how different processing conditions of the composite affect the compatibility of polymer and additive. How well the polymer composites perform compared to targeted performance values is evaluated, and an analysis is completed to determine the specific effect each additive has on the outcome of the polymer composites performance. The thesis provided a basis of knowledge behind the mechanisms of flame retardant additives, and supplied information on how different additives could be used in a multitude of polymer matrices. The work also demonstrated the effectiveness of phosphorus based and nitrogen based flame retardants had on the flame retardancy and thermal stability of a polyolefin matrix blend. This study focused on a small segment of the large variety of flame retardant additives available to use, in a multitude of differing variations. The research into developing flame retardant systems is an expanding field.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.027
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.023
GPT teacher head0.301
Teacher spread0.277 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2024
Admission routes1
Has abstractyes

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