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Record W7132971283

Structural and Mechanistic Characterization of Type II-C Anti-CRISPR Proteins

2023· dissertation· W7132971283 on OpenAlexaff
Sungwon Hwang

Bibliographic record

VenueTSpace · 2023
Typedissertation
Language
FieldBiochemistry, Genetics and Molecular Biology
TopicCRISPR and Genetic Engineering
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsCas9CleaveCRISPRDNAGenomeMutagenesisStructural biologyGeneChemical biologySynthetic biology
DOInot available

Abstract

fetched live from OpenAlex

The CRISPR-Cas adaptive immune system provides bacteria with defence against phage predation.CRISPR-Cas systems use protein-RNA complexes to cleave and eliminate invading phage genomes in a sequence specific manner. Phages have evolved a countermeasure through the expression of small protein inhibitors against CRISPR-Cas called “anti-CRISPRs”. Anti-CRISPR proteins use incredibly diverse mechanisms to either bind directly to or enzymatically modify Cas proteins to prevent cleavage mediated by CRISPR-Cas. CRISPR-Cas enzymes, especially Cas9, have been repurposed in many biotechnologies including genome editing. Anti-CRISPRs have potential to be utilized as “off-switches” for CRISPRCas9 gene editing, addressing safety and ethical concerns for the technology. Since their discovery in 2013, over 90 protein families of anti-CRISPRs have been reported, with 37 being inhibitors of Cas9 specifically. However, much of the mechanistic details of the anti-CRISPR proteins are left incomplete. In this thesis work, I characterize the inhibitory mechanisms of two CRISPR-Cas9 inhibitors, AcrIIC4 and AcrIIC5, using structural biology and biochemical and biophysical assays. I demonstrate that AcrIIC4 inhibits the DNA cleavage activity of Cas9 by binding to the REC2 domain of Cas9 and preventing the conformational changes required for Cas9 to switch into the active state, while AcrIIC5 inhibits Cas9 from binding to target DNA using DNA mimicry. The inhibitory mechanisms elucidated in my thesis work can be applied to the potential development of AcrIIC4 and AcrIIC5 for biotechnological purposes. This work also expands our knowledge of the vast arsenal phages have evolved to circumvent CRISPRCas defence.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.006

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.325
Teacher spread0.315 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2023
Admission routes1
Has abstractyes

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