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Preparation of liposomes using supercritical carbon dioxide technology: Effects of phospholipids and sterols

2015· article· en· W803825273 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueFood Research International · 2015
Typearticle
Languageen
FieldEngineering
TopicPhase Equilibria and Thermodynamics
Canadian institutionsUniversity of Alberta
FundersNatural Sciences and Engineering Research Council of CanadaAlberta Innovates - Technology Futures
KeywordsPhospholipidLiposomeZeta potentialEgg lecithinChemistryParticle sizeLecithinSupercritical carbon dioxideChromatographySterolDispersityVesicleSolventPhosphatidylcholineSupercritical fluidAnalytical Chemistry (journal)MembraneChemical engineeringOrganic chemistryCholesterolMaterials scienceNanotechnologyBiochemistryNanoparticle

Abstract

fetched live from OpenAlex

Liposomes were prepared utilizing a supercritical carbon dioxide (SC-CO 2 ) process. A phospholipid suspension was first equilibrated with CO 2 at 300 bar and then depressurized at a constant pressure and rate. The effects of phospholipid concentration, phospholipid type, sterol concentration and sterol type on particle size, uniformity, zeta potential and morphology were investigated. With increasing soy lecithin concentration (5–30 mM) at 50 °C, the smallest particle size of liposomes (146.1 ± 0.8 nm) was obtained at 30 mM with the polydispersity index (PdI) of 0.398 ± 0.008. Increased phospholipid concentration was favorable for the formation of smaller size vesicles with higher uniformity. Longer chain length of fatty acids in pure phospholipids resulted in a larger particle size with more spherical shape while a phospholipid with unsaturated fatty acyl chains resulted in increased asymmetry. With elevated β-sitosterol concentration (10%–50%), particle size and PdI increased to 245.5 ± 7.14 nm and 0.514 ± 0.018, respectively, with decreased absolute zeta potential . 6-Ketocholestanol showed the smallest diameter and PdI of liposomes with the most spherical shape among all sterol types tested. Soy lecithin exhibited the highest stability of vesicular systems due to its highest absolute zeta potential (− 58.3 ± 2.17 mV) among all the phospholipid types. The SC-CO 2 method demonstrated superior characteristics of liposomes over traditional thin film hydration method for a smaller size and PdI as well as enhanced intactness without leakage. It might offer a promising way to reduce usage of sterol in liposome formulations while eliminating organic solvent usage.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.201
Threshold uncertainty score0.248

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.045
GPT teacher head0.364
Teacher spread0.319 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it