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Record W2024755417 · doi:10.1021/ie010377t

Total Internal Reflection Microscopy:  Distortion Caused by Additive Noise

2001· article· en· W2024755417 on OpenAlexfundno aff
Paul C. Odiachi, Dennis C. Prieve

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2001
Typearticle
Languageen
FieldEngineering
TopicMicrofluidic and Bio-sensing Technologies
Canadian institutionsnot available
FundersSyncrudePPG IndustriesNational Science Foundation
KeywordsDistortion (music)Standard deviationTotal internal reflectionOpticsIntensity (physics)PhysicsMolecular physicsReflection (computer programming)ChemistryBrownian motionScatteringColloidMicroscopyQuantum mechanicsMathematics

Abstract

fetched live from OpenAlex

Total internal reflection microscopy (TIRM) is an optical technique for monitoring Brownian fluctuations in the separation between a single microscopic sphere and a flat plate in aqueous media. The sphere is levitated above the plate by colloidal forces such as double-layer or steric repulsion. Changes in elevation as small as 1 nm can be detected by measuring the light scattered by a single sphere when illuminated by an evanescent wave. From the Boltzmann distribution of elevations sampled by the sphere over a long time, the potential energy (PE) profile can be determined with a resolution of about 0.1 kT . By corrupting clean data (having a mean scattering intensity of Ī s and a standard deviation of σ s ) obtained by Brownian dynamics simulations with various levels of additive background noise (having a mean background intensity of Ī b and a standard deviation of σ b ), we show how the PE profiles obtained from TIRM are distorted. Increasing Ī b narrows the profile and shifts it toward smaller elevations; conversely, increasing σ b broadens the PE profile. Subtracting Ī b from the measured total intensities before analysis removes much of the distortion. The extent of remaining distortion (broadening) depends primarily on the ratio σ b /σ s and can be neglected when this ratio is less than 0.15.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.016
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.049
GPT teacher head0.309
Teacher spread0.259 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations7
Published2001
Admission routes1
Has abstractyes

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