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Record W2169377754 · doi:10.17760/d20002134

Laminar burning speed and flame structure of 1,1-difluoroethane (HFC-152a)/air and difluoromethane (HFC-32)/air mixtures

2011· dissertation· en· W2169377754 on OpenAlexaboutno aff
Casey Bennett

Bibliographic record

Venuenot available
Typedissertation
Languageen
FieldChemistry
TopicChemical Thermodynamics and Molecular Structure
Canadian institutionsnot available
Fundersnot available
KeywordsRefrigerantASHRAE 90.1DifluoromethaneFlammable liquidRefrigerationMontreal ProtocolAir conditioningFlammabilityLaminar flowWaste managementEnvironmental scienceGlobal-warming potentialEngineeringOzone layerOzoneMeteorologyChemistryMechanical engineeringAerospace engineeringGas compressorGreenhouse gas

Abstract

fetched live from OpenAlex

Of recent importance is the laminar burning speed of hydrofluorocarbons (HFCs) used in the refrigerant industry. Since the adoption of the Montreal Protocol in 1989 and the Kyoto Protocol in 1997 there has been an ongoing phase-out of chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) which deplete the ozone layer. Refrigerant companies are working to develop alternatives to CFC and HCFC based chemicals that have long been used in air conditioning and refrigeration systems. Alternatives that are currently in use include HFCs such as (HFC-134a); however HFC-134a has recently been deemed an environmental danger as well and will be phased out accordingly. Other HFCs with desirable thermodynamic properties are potential replacements but they are flammable and so the potential for ignition must be evaluated very carefully. The American Society of Heating, Refrigeration, and Air-Conditioning Engineers (ASHRAE) and the International Organization for Standardization (ISO) are finalizing a new international standard that specifies that laminar burning speed will be the parameter that classifies a chemical as being mildly flammable.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.009

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0030.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.219
Teacher spread0.214 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations7
Published2011
Admission routes1
Has abstractyes

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