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Record W2327146738 · doi:10.1021/acs.iecr.5b03964

A Promising Surfactant for Enhanced Sorption and Desorption of Polycyclic Aromatic Hydrocarbons

2016· article· en· W2327146738 on OpenAlexaff
Jia Wei, Guohe Huang, Jun Li, Xiujie Wang

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2016
Typearticle
Languageen
FieldChemistry
TopicSurfactants and Colloidal Systems
Canadian institutionsUniversity of Regina
FundersChina Postdoctoral Science FoundationNational Natural Science Foundation of ChinaChinese Academy of SciencesNational Science Foundation
KeywordsPulmonary surfactantSorptionChemistryEnvironmental remediationDesorptionAdsorptionEnvironmental chemistryMicelleCationic polymerizationSoil waterChemical engineeringSoil contaminationAqueous solutionAmphiphileAqueous two-phase systemOrganic chemistryContaminationEnvironmental scienceSoil science

Abstract

fetched live from OpenAlex

Gemini surfactants, an innovative class of amphiphilic molecules, are of increasingly scientific interest due in part to their effectiveness in soil/water remediation. This study was carried out to investigate the overall partitioning of three representative polycyclic aromatic hydrocarbons (PAHs) in the soil-water–surfactant system which takes into consideration the soil-sorbed cationic Gemini surfactant, presence of Gemini micelles, and related developed coefficients. The results indicated that the adsorption of Gemini surfactants onto soil particles through both cation exchange and hydrophobic interaction contribute to the bi or multilayer formation. The sorbed C 12–3–12 studied herein, is a highly effective partitioning media for PAHs to adsorb onto the soil phase from the aqueous phase and thus, can be considered as a good adjuvant for an enhanced sorption zone. The partitioning behavior of PAHs in the soil–water–Gemini surfactant has a strong relationship with their K ow . The experimental results from this research will be used to gain an understanding of the effect of cationic Gemini surfactant on the distribution of HOCs in a soil-water system and provide some fundamental and valuable information in remediation of contaminated soils and waters.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.619

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.073
GPT teacher head0.306
Teacher spread0.232 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations11
Published2016
Admission routes1
Has abstractyes

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