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Record W2327229304 · doi:10.1021/ef500021y

Migration of Fine Solids into Product Bitumen from Solvent Extraction of Alberta Oilsands

2014· article· en· W2327229304 on OpenAlexaffabout
Hossein Nikakhtari, Sebastian Wolf, Phillip Choi, Qi Liu, Murray R. Gray

Bibliographic record

VenueEnergy & Fuels · 2014
Typearticle
Languageen
FieldChemistry
TopicPetroleum Processing and Analysis
Canadian institutionsUniversity of Alberta
Fundersnot available
KeywordsAsphaltTotal dissolved solidsOil sandsExtraction (chemistry)Carbon fibersChemistrySuspended solidsTotal organic carbonTailingsChemical engineeringMineralogyEnvironmental chemistryMaterials scienceMetallurgyChromatographyWastewaterWaste managementEnvironmental engineeringComposite material

Abstract

fetched live from OpenAlex

The extraction of bitumen from the oilsands using solvents has the potential to avoid the environmental problems with wet tailings associated with water-based extraction technology. One of the key performance parameters for this technology is the concentration of fine solids in the recovered bitumen. In this study, the concentration and properties of the fine solids in cyclohexane-extracted bitumen were examined as a function of the water content of the ore. Total water contents from 3.4–13.4 wt % gave the lowest concentrations of fine solids in the bitumen, ca. 0.2 wt % of the initial mass of a low-fines content ore. Higher fine solids contents in the bitumen were observed with water concentrations outside this range and with higher concentrations of fine solids in the initial oilsands ore. The fine solids exhibited a distribution of surface properties, and the most hydrophobic, carbon rich solids were carried into the bitumen even under the most favorable conditions. When the bitumen was more contaminated with fine solids, due to higher fines in the ore or lack of water to bind the fines to the sand, the carbon content of the fine solids decreased. The majority of the carbon in the fine solids was organic material due to bitumen and surface adsorbed components. Despite carbon contents over 20 wt %, XPS analysis showed significant surface silicon and aluminum, and contact angles were in the range of 80–88°, consistent with partial organic coating of the mineral particles. Characterization of the fine solids by SEM, particle size, and mineralogy suggested that the migration of the fine solids into the bitumen, versus remaining with the coarse sand, was significantly affected by the organic surface deposits on the particles.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.037
Threshold uncertainty score0.996

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.231
Teacher spread0.224 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations47
Published2014
Admission routes2
Has abstractyes

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