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Record W2485350468 · doi:10.1007/978-1-61779-915-0_8

Immobilization of Fluorescent Aptamer Biosensors on Magnetic Microparticles and Its Potential Application for Ocean Sensing

2012· book-chapter· en· W2485350468 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueSpringer protocols handbooks/Springer protocols · 2012
Typebook-chapter
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicAdvanced biosensing and bioanalysis techniques
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsAptamerBiosensorAnalyteFluorescenceNucleic acidIonic strengthNanotechnologyChemistrySalt (chemistry)Combinatorial chemistryChromatographyBiochemistryMaterials scienceBiologyMolecular biologyAqueous solutionOrganic chemistry

Abstract

fetched live from OpenAlex

Many important analytes are present in the ocean water and primary examples include various marine toxins. The unique marine environment possesses an extremely high ionic strength, posing a significant analytical challenge for biosensor design. Protein-based enzymes and antibodies are likely to denature under such non-physiological conditions. Aptamers are nucleic acid-based binding molecules that can be obtained using a combinatorial in vitro selection technique. Since such selections are carried out in the absence of living cells, it is possible to obtain aptamers that work optimally under high salt conditions. Similarly selections in low pH and high temperatures have already been carried out. The high salt concentration in marine samples may also cause significant fluorescence quenching, reducing the sensitivity of fluorescent aptamer sensors. We propose that this problem may be solved by immobilization of aptamer-based biosensors on magnetic microparticles, allowing spatial separation of the target binding and the fluorescence detection steps. In this chapter, we describe a protocol for the detection of adenosine and ATP in high salt buffers and in human blood serum. Compared to the non-immobilized sensor, more consistent results with reduced interference were achieved after immobilization. Future research directions of using such immobilized sensors for marine detection are also discussed.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Protocol · Consensus signal: Protocol
Teacher disagreement score0.383
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.020
GPT teacher head0.291
Teacher spread0.271 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it