The broadening reach of frustrated Lewis pair chemistry
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Abstract
The revelation that combinations of Lewis acids and bases for which dative bonding is impeded can activate dihydrogen led to the concept of "frustrated Lewis pairs" (FLPs). Over the past decade, a range of FLP systems and substrate molecules have precipitated a paradigm change in main-group chemistry and metal-free catalysis. The FLP motif has also found application in a growing body of chemical problems in organic synthesis, transition metal and free radical chemistry, materials, enzymatic models, and surface chemistry. The current state of FLP chemistry is assessed herein, and the outlook for the future considered.
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The record
- Venue
- Science
- Topic
- Organoboron and organosilicon chemistry
- Field
- Chemistry
- Canadian institutions
- University of Toronto
- Funders
- Natural Sciences and Engineering Research Council of CanadaCanada Research Chairs
- Keywords
- Frustrated Lewis pairChemistryLewis acids and basesCatalysisMoleculeTransition metalCombinatorial chemistryOrganic chemistry
- Has abstract in OpenAlex
- yes