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High Throughput Screening of Protein Arginine <i>N</i> ‐Methyltransferases – Filter Binding and Phosphor Screening (FBAPS) assay

2022· article· en· W4225377973 on OpenAlexaff
Michael J. Rowley, Shona A. Taylor, Adam Frankel

Bibliographic record

VenueThe FASEB Journal · 2022
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicCancer-related gene regulation
Canadian institutionsUniversity of VictoriaUniversity of British Columbia
Fundersnot available
KeywordsArginineHigh-throughput screeningMethyltransferaseChemistryLigand binding assayWestern blotEnzymeBiochemistryMethylationAmino acidReceptor

Abstract

fetched live from OpenAlex

Study Objective We seek to develop a cost‐effective assay to screen protein arginine N‐ methyltransferase (PRMT) enzyme activity in a high throughput manner by combining P81 filter binding with phosphor imaging. Hypothesis A combination of the P81 filter binding assay and phosphor screening (FBAPS) will provide improved throughput for testing inhibitors against PRMTs while eliminating the economic and environmental costs incurred with current PRMT assays. Statement of methods Recombinantly‐expressed PRMT1 and coactivator‐associated arginine methyltransferase 1 (CARM1) were used to develop the FBAPS assay using GST fusions of polyA binding protein 1 (PABP1(437‐488)) and glycine‐ and arginine‐rich (GAR) protein as substrates, respectively, and radiolabelled S ‐adenosyl‐L‐[ methyl ‐ 14 C]‐methionine as cofactor. Methylation reactions were spotted onto P81 filter paper in a dot blot apparatus and radioactive signal was measured both by phosphor imaging and liquid scintillation counting. Kinetic parameters (K M , k cat ) for enzymes and substrates were determined, and IC 50 values were obtained for well‐characterized inhibitors S ‐adenosyl‐L‐homocysteine (SAH), MS023, EPZ020411, and Diamine 12 using FBAPS. Summary of Results FBAPS yielded kinetic parameters with no statistically significant differences to what was obtained using liquid scintillation counting. The IC 50 values obtained by the FBAPS assay for PRMT1 and CARM1 were comparable to values reported in literature. Statement of Conclusions The FBAPS assay is a modification to the P81 filter binding assay with a dot blot apparatus that allows for parallel processing of samples in a multi‐well format, dramatically increasing throughput. Signal detection by phosphor imaging offers a cost effective and quantitative method that can be used to screen several inhibitors simultaneously against PRMT enzymes with high accuracy.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.007

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0020.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.230
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

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Citations0
Published2022
Admission routes1
Has abstractyes

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