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Record W4401868077 · doi:10.1021/jacs.4c02354

RNA-Activated CRISPR/Cas12a Nanorobots Operating in Living Cells

2024· article· en· W4401868077 on OpenAlexaff
Aijiao Yuan, Rui Sha, Wenjing Xie, Guangbo Qu, Hongquan Zhang, Hailin Wang, X. Chris Le, Guibin Jiang, Hanyong Peng

Bibliographic record

VenueJournal of the American Chemical Society · 2024
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicCRISPR and Genetic Engineering
Canadian institutionsUniversity of Alberta
FundersNational Key Research and Development Program of ChinaChinese Academy of SciencesNational Natural Science Foundation of China
KeywordsTrans-activating crRNACRISPRRNAChemistryNanoroboticsCleavage (geology)RibonucleoproteinCas9Guide RNANucleic acidComputational biologyCell biologyGeneBiologyBiochemistryNanotechnology

Abstract

fetched live from OpenAlex

Active clustered regularly interspaced short palindromic repeats (CRISPR/Cas12a) systems possess both cis -cleavage (targeted) and trans -cleavage (collateral) activities, which are useful for genome engineering and diagnostic applications. Both single- and double-stranded DNA can activate crRNA–Cas12a ribonucleoprotein (RNP) to achieve cis - and trans -cleavage enzymatic activities. However, it is not clear whether RNA can activate the CRISPR/Cas12a system and what is critical to the trans -cleavage activity. We report here that RNA can activate the CRISPR/Cas12a system and trigger its trans -cleavage activity. We reveal that the activated crRNA–Cas12a RNP favors the trans -cleavage of longer sequences than commonly used. These new findings of the RNA-activated trans -cleavage capability of Cas12a provided the foundation for the design and construction of CRISPR nanorobots that operate in living cells. We assembled the crRNA–Cas12a RNP and nucleic acid substrates on gold nanoparticles to form CRISPR nanorobots, which dramatically increased the local effective concentration of the substrate in relation to the RNP and the trans -cleavage kinetics. Binding of the target microRNA to the crRNA–Cas12a RNP activated the nanorobots and their trans -cleavage function. The repeated (multiple-turnover) trans -cleavage of the fluorophore-labeled substrates generated amplified fluorescence signals. Sensitive and real-time imaging of specific microRNA in live cells demonstrated the promising potential of the CRISPR nanorobot system for future applications in monitoring and modulating biological functions within living cells.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.287
Teacher spread0.281 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations85
Published2024
Admission routes1
Has abstractyes

Explore more

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