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The effect of flocculant anionicity on the resistance of quartz flocs to mechanical treatment

2024· article· en· W4403409787 on OpenAlexafffund
Hamid Alizadeh, Marek Pawlik

Bibliographic record

VenueColloids and Surfaces A Physicochemical and Engineering Aspects · 2024
Typearticle
Languageen
FieldEnvironmental Science
TopicCoagulation and Flocculation Studies
Canadian institutionsUniversity of British Columbia
FundersNational Research Council CanadaMitacs
KeywordsFlocculationQuartzMaterials scienceResistance (ecology)Chemical engineeringChemistryComposite materialEngineeringBiology

Abstract

fetched live from OpenAlex

Five polyacrylamide (PAM)-based flocculants of similar molecular weights but different degrees of anionicity were selected to investigate the effect of physicochemical properties of the tested polymers on resistance of quartz flocs to mechanical treatment. The flocculated quartz suspension was prepared at two different flocculant dosages and each sample was subjected to either ultrasonication or screening to break the flocs. The tests were performed as a function of ultrasonication duration and screen size while settling rate of flocs, turbidity of supernatant and adsorption density of flocculants were measured as indices of strength of flocs. Adsorption studies showed that adsorption density of flocculants on fine quartz surface remained unaffected by ultrasonication and screening tests, indicating that the observed changes in floc sizes was not a result of desorption. It was found that ultrasonication not only breaks the flocs but also affects the polymer chain, while screening as a strength measurement technique only breaks the flocs. In relation to dewatering applications that rely on floc strength to allow water to flow freely, such as pressure filtration, it was found that at the same adsorption density of the flocculants, PAMs with flexible chains produced the most resistant flocs. These results are attributed to the ability of these flocculants to conform to the shape and size of the flocs. • Effect of five PAM samples on strength of quartz flocs was studied. • Polymer samples were of known molecular weight and degree of anionicity. • Ultrasonication and screening were used to break the flocs. • Screening was a more appropriate strength measuring technique than ultrasonication. • Correlation was shown between flocs strength and flexibility of polymers.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.191
Threshold uncertainty score0.186

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.210
Teacher spread0.204 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2024
Admission routes2
Has abstractyes

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