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Record W4412800523 · doi:10.1016/j.rinp.2025.108368

Two-step laser resonant ionization spectroscopy of neutral chromium

2025· article· en· W4412800523 on OpenAlexafffund
R. Schulz, Ruohong Li, Julius Wessolek, Maryam Mostamand, P. Kunz, J. Lassen

Bibliographic record

VenueResults in Physics · 2025
Typearticle
Languageen
FieldChemistry
TopicAnalytical chemistry methods development
Canadian institutionsUniversity of ManitobaUniversity of WindsorSimon Fraser UniversitySaint Mary's UniversityTRIUMF
FundersNational Research Council CanadaNatural Sciences and Engineering Research Council of CanadaTRIUMF
KeywordsChromiumIonizationAtomic physicsSpectroscopyLaserMaterials scienceAtmospheric-pressure laser ionizationPhysicsPhotoionizationIonOpticsQuantum mechanics

Abstract

fetched live from OpenAlex

At TRIUMF’s off-line laser ion source test stand, stepwise resonant laser ionization spectroscopy of neutral chromium (Cr I) was carried out, to find an efficient ionization scheme suitable for titanium sapphire (Ti:Sa) laser systems. With the excitation to the three different intermediate levels, 27728.811 cm −1 , 27820.198 cm −1 , and 27935.241 cm −1 , automated continuous laser-frequency scans using a frequency-doubled, grating-tuned Ti:Sa laser were performed. Rydberg series as well as autoionizing (AI) states were observed. From these results, the ionization potential (IP) of Cr I was determined as 54575.49(2) stat (3) sys cm −1 , which is one order of magnitude more precise than the previously reported 54575.6(3) cm −1 in NIST database. The ionization scheme using the observed AI resonance, λ 1 , v a c = 357.971 nm + λ 2 , v a c = 373.935 nm, was subsequently deployed to the online delivery of radioactive Cr + isotope beams for precision mass measurements. The online yields of 50 − 59 Cr + have been measured at TRIUMF-ISAC. • The ionization potential of chromium is determined with increased precision. • An efficient two-step resonant laser ionization scheme via an autoionizing resonance has been developed. • Radioactive Cr isotope beam yields using the two-step resonant laser ionization scheme were measured.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.006

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.306
Teacher spread0.291 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes2
Has abstractyes

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Same venueResults in PhysicsSame topicAnalytical chemistry methods developmentFrench-language works237,207