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Record W4416447621 · doi:10.1021/jacsau.5c00827

Harnessing Bone-Liver Crosstalk: A Dual-Action LYTAC Approach for Bone-Specific Accumulation and Liver-Specific Protein Degradation in Bone Disorders

2025· article· en· W4416447621 on OpenAlex
Yuan Ma, Amu Gubu, Yufei Pan, Hewen Jiang, Sifan Yu, Huarui Zhang, Zefeng Chen, Hang Luo, Chuanxin Zhong, Xin Yang, Xiaohui Tao, Yihao Zhang, Yuanyuan Yu, Aiping Lü, Luyao Wang, Bao‐Ting Zhang, Ge Zhang

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueJACS Au · 2025
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicProtein Degradation and Inhibitors
Canadian institutionsGovernment of Northwest Territories
FundersNatural Science Foundation of Zhejiang ProvinceResearch Grants Council, University Grants CommitteeNational Natural Science Foundation of ChinaFirst Affiliated Hospital of Zhengzhou UniversityHunan Provincial Science and Technology DepartmentHong Kong Baptist University
KeywordsSclerostinWnt signaling pathwayOsteogenesis imperfectaBone formationAptamerProtein degradationMesenchymal stem cellMechanism (biology)LRP5

Abstract

fetched live from OpenAlex

High Resolution Image Download MS PowerPoint Slide Despite significant progress in extracellular targeted protein degradation (eTPD), existing approaches rarely achieved tissue-specific drug accumulation while maintaining efficient systemic clearance, a critical challenge in treating bone disorders. In this study, we introduced GalNAc-Apc001, a novel aptamer-based lysosome-targeting chimera (LYTAC) that uniquely combined bone-specific retention with hepatocyte-mediated clearance through a spatiotemporally controlled mechanism. By conjugating a tri-N-acetylgalactosamine (GalNAc) moiety to a bone-homing sclerostin aptamer (Apc001), we engineered a bifunctional molecule capable of accumulating in bone via hydroxyapatite binding, capturing circulating sclerostin with high affinity and directing it to hepatocytes for ASGPR-mediated lysosomal degradation. In the absence of ASGPR-positive cells, GalNAc-Apc001 functioned via the conventional aptamer mechanism of binding inhibition, demonstrating efficacy comparable to that of Apc001 but notably lower than that of a sclerostin antibody. However, in ASGPR-positive cell coculture systems, GalNAc-Apc001 achieved a 40% greater activation of the Wnt signaling pathway compared to the sclerostin antibody, effectively reversing sclerostin-mediated inhibition (96 vs 60% recovery). Pharmacologically, GalNAc-Apc001 exhibited superior therapeutic efficacy by mitigating the suppressive effects of sclerostin on Wnt signaling, upregulating bone formation markers, and enhancing bone mass in a Col1a2 +/G610C osteogenesis imperfecta mouse model. These findings provided compelling mechanistic evidence that the spatiotemporal control of protein degradation could resolve the inherent trade-off between tissue targeting and systemic clearance, supporting the clinical potential of GalNAc-Apc001 in bone disorders.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.308
Threshold uncertainty score0.877

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.036
GPT teacher head0.289
Teacher spread0.253 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it